Ваша модель NowPlaying содержит данные для объекта только в одном воспроизводимом сейчас результате. Если вы посмотрите на ответ, как в примере на сайте: https://developers.themoviedb.org/3/movies/get-now-playing
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Вы видите, что он обернут в results объект. Итак, вам нужно что-то вроде этого:
public class RootObject
{
public NowPlaying[] Results { get; set; }
}
И десериализовать в RootObject. Отличным инструментом для получения структуры объекта JSON является quicktype.io . Или даже запекается в Visual Studio (только для Windows). Скопируйте объект JSON и перейдите к Редактировать > Специальная вставка > Вставить JSON как классы
