Проблема была в изменении времени в Чили, большое спасибо.
+-------------------+---------+
| DateIntermedia|TimeStamp|
+-------------------+---------+
|13-08-2017 00:01:07| null|
|13-08-2017 00:10:33| null|
|14-08-2016 00:28:42| null|
|13-08-2017 00:04:43| null|
|13-08-2017 00:33:51| null|
|14-08-2016 00:28:08| null|
|14-08-2016 00:15:34| null|
|14-08-2016 00:21:04| null|
|13-08-2017 00:34:13| null|
+-------------------+---------+
Решение, установить timeZone:
spark.conf.set("spark.sql.session.timeZone", "UTC-6")