Я не могу воспроизвести упомянутую вами проблему:
Welcome to Scala version 2.7.4.final (Java HotSpot(TM) Client VM, Java 1.6.0_16).
Type in expressions to have them evaluated.
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scala> val map1 = ( ('A' to 'Z') ++ ('a' to 'z') ++ ('0' to '9') ).toArray ++ Array('+', '/')
map1: Array[Char] = Array(A, B, C, D, E, F, G, H, I, J, K, L, M, N, O, P, Q, R, S, T, U, V, W, X, Y, Z, a, b, c, d, e, f
, g, h, i, j, k, l, m, n, o, p, q, r, s, t, u, v, w, x, y, z, 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, +, /)
scala> val map1 = (
| ('A' to 'Z') ++ ('a' to 'z') ++ ('0' to '9')
| ).toArray ++ Array('+', '/');
map1: Array[Char] = Array(A, B, C, D, E, F, G, H, I, J, K, L, M, N, O, P, Q, R, S, T, U, V, W, X, Y, Z, a, b, c, d, e, f
, g, h, i, j, k, l, m, n, o, p, q, r, s, t, u, v, w, x, y, z, 0, 1, 2, 3, 4, 5, 6, 7, 8, 9, +, /)