Да, просто используйте кодирование значения ключа, чтобы запросить значения ключа:
NSArray* names = [NSArray arrayWithObjects:
[NSDictionary dictionaryWithObjectsAndKeys:
@"Joe",@"firstname",
@"Bloggs",@"surname",
nil],
[NSDictionary dictionaryWithObjectsAndKeys:
@"Simon",@"firstname",
@"Templar",@"surname",
nil],
[NSDictionary dictionaryWithObjectsAndKeys:
@"Amelia",@"firstname",
@"Pond",@"surname",
nil],
nil];
//use KVC to get the names
NSArray* firstNames = [names valueForKey:@"firstname"];
NSLog(@"first names: %@",firstNames);