С макушки головы я думаю, что это похоже на
ProductCategory category = null;
var result = Session.QueryOver<Product>()
.JoinAlias(x => x.Categories, () => category, JoinType.LeftOuterJoin)
.Where(() => category.SubType == "Premium")
.OrderBy(() => category.Sequence).Desc
.Take(1)
.List();
Редактировать: включил OrderBy и дал ему тест. Работает.
Используя пример типа Blog> Posts, сгенерированный SQL выглядит так:
SELECT this_.Id as Id1_1_,
this_.Title as Title1_1_,
post1_.BlogId as BlogId3_,
post1_.Id as Id3_,
post1_.Id as Id3_0_,
post1_.Title as Title3_0_,
post1_.Content as Content3_0_,
post1_.DatePosted as DatePosted3_0_,
post1_.BlogId as BlogId3_0_
FROM [Blog] this_
left outer join [Post] post1_
on this_.Id = post1_.BlogId
WHERE post1_.DatePosted > '2011-11-22T19:43:11.00' /* @p0 */
ORDER BY post1_.DatePosted desc