Попробуйте:
d = {}
for i in combo:
s = set(teams) - set(i)
d[i] = [list(s)[k:k+2] for k in range(0, len(s), 2)]
Вывод :
{(5, 9): [[1, 2], [3, 4], [6, 7], [8, 10]], (4, 7): [[1, 2], [3, 5], [6, 8], [9, 10]], (1, 3): [[2, 4], [5, 6], [7, 8], [9, 10]], (4, 8): [[1, 2], [3, 5], [6, 7], [9, 10]], (5, 6): [[1, 2], [3, 4], [7, 8], [9, 10]], (2, 8): [[1, 3], [4, 5], [6, 7], [9, 10]], (6, 9): [[1, 2], [3, 4], [5, 7], [8, 10]], (8, 9): [[1, 2], [3, 4], [5, 6], [7, 10]], (1, 6): [[2, 3], [4, 5], [7, 8], [9, 10]], (3, 7): [[1, 2], [4, 5], [6, 8], [9, 10]], (2, 5): [[1, 3], [4, 6], [7, 8], [9, 10]], (5, 8): [[1, 2], [3, 4], [6, 7], [9, 10]], (1, 2): [[3, 4], [5, 6], [7, 8], [9, 10]], (4, 9): [[1, 2], [3, 5], [6, 7], [8, 10]], (2, 9): [[1, 3], [4, 5], [6, 7], [8, 10]], (3, 10): [[1, 2], [4, 5], [6, 7], [8, 9]], (6, 10): [[1, 2], [3, 4], [5, 7], [8, 9]], (8, 10): [[1, 2], [3, 4], [5, 6], [7, 9]], (1, 5): [[2, 3], [4, 6], [7, 8], [9, 10]], (3, 6): [[1, 2], [4, 5], [7, 8], [9, 10]], (1, 10): [[2, 3], [4, 5], [6, 7], [8, 9]], (7, 9): [[1, 2], [3, 4], [5, 6], [8, 10]], (4, 10): [[1, 2], [3, 5], [6, 7], [8, 9]], (2, 6): [[1, 3], [4, 5], [7, 8], [9, 10]], (7, 10): [[1, 2], [3, 4], [5, 6], [8, 9]], (4, 5): [[1, 2], [3, 6], [7, 8], [9, 10]], (1, 4): [[2, 3], [5, 6], [7, 8], [9, 10]], (2, 10): [[1, 3], [4, 5], [6, 7], [8, 9]], (9, 10): [[1, 2], [3, 4], [5, 6], [7, 8]], (3, 9): [[1, 2], [4, 5], [6, 7], [8, 10]], (2, 3): [[1, 4], [5, 6], [7, 8], [9, 10]], (1, 9): [[2, 3], [4, 5], [6, 7], [8, 10]], (6, 8): [[1, 2], [3, 4], [5, 7], [9, 10]], (6, 7): [[1, 2], [3, 4], [5, 8], [9, 10]], (3, 5): [[1, 2], [4, 6], [7, 8], [9, 10]], (2, 7): [[1, 3], [4, 5], [6, 8], [9, 10]], (5, 10): [[1, 2], [3, 4], [6, 7], [8, 9]], (4, 6): [[1, 2], [3, 5], [7, 8], [9, 10]], (7, 8): [[1, 2], [3, 4], [5, 6], [9, 10]], (5, 7): [[1, 2], [3, 4], [6, 8], [9, 10]], (3, 8): [[1, 2], [4, 5], [6, 7], [9, 10]], (1, 8): [[2, 3], [4, 5], [6, 7], [9, 10]], (1, 7): [[2, 3], [4, 5], [6, 8], [9, 10]], (3, 4): [[1, 2], [5, 6], [7, 8], [9, 10]], (2, 4): [[1, 3], [5, 6], [7, 8], [9, 10]]}