Я думаю, что вам нужно это, как сказал @jarlh 'Overdue Day(s)'
- это строка, в которой вы не можете выполнять математические операции.
SELECT DVD_mem_id AS 'Member ID',
DVD_mem_name AS 'Member Name',
DVD_movie_id AS 'Movie ID',
DVD_movie_title AS 'Movie Title',
DVD_borrowing_date AS 'Date of Borrow',
DVD_date_due AS 'Date Due',
CAST((DATEDIFF(DAY, DVD_borrowing_date, DVD_date_due) -3) AS int),
DATEDIFF(DAY, DVD_borrowing_date, DVD_date_due) -3 AS 'Overdue Day(s)',
(DATEDIFF(DAY, DVD_borrowing_date, DVD_date_due) -3) * 2 AS 'Fine Incurred'
FROM DVD_T
WHERE (DVD_mem_id IS NOT NULL) AND
(DVD_mem_name IS NOT NULL) AND
(DVD_borrowing_date IS NOT NULL) AND
(DVD_date_due) IS NOT NULL AND
(DATEDIFF(DAY, DVD_borrowing_date, DVD_date_due) -3 > 0)