Надеюсь, это поможет, вам сначала нужно переставить информацию, содержащуюся в словаре, и сохранить ее в pandas Excel Writer
import pandas as pd
dic = {'66': 74, '62': 32, '69': 18, '72': 14, '64': 37, '192': 60, '51': 70, '46': 42, '129': 7, '85': 24, '83': 73, '65': 14, '87': 28, '185': 233, '171': 7, '176': 127, '89': 42, '80': 32, '5':
54, '93': 56, '104': 53, '138': 7, '162': 28, '204': 28, '79': 46, '178': 60, '144': 21, '90': 136, '193': 42, '88': 52, '212': 22, '199': 35, '198': 21, '149': 22, '84': 82, '213': 49, '47': 189, '195': 46, '31': 152, '71': 21, '70': 4, '207': 7, '158': 14, '109': 7, '163': 46, '142': 14, '94': 14, '173': 11, '78': 7, '134': 7, '96': 7, '128': 7, '54': 14, '63': 4, '120': 28, '121': 7, '37': 22, '13': 7, '45': 14, '23': 10, '180': 7, '50': 14, '188': 35, '24': 7, '139': 18, '148': 12, '151': 4, '2': 18, '34': 4, '77': 32, '81': 44, '82': 11, '92': 19, '95': 29, '98': 7, '217': 21, '172': 14, '35': 148, '146': 7, '91': 21, '103': 21, '184': 28, '165': 7, '108': 7, '112': 7, '118': 7, '159': 7, '183': 7, '186': 7, '205': 7, '60': 7, '67': 7, '76': 7, '86': 7, '209': 7, '174': 7, '194': 1}
table = pd.DataFrame(dic, index=[0])
y = [int(item) for item in table.columns.tolist()]
table.loc[1] = table.loc[0]
table.loc[0] = y
table = table.transpose()
table.columns = ['Start', 'Quantity']
table.index = list(range(len(table.index)))
writer = pd.ExcelWriter('output.xlsx')
table.to_excel(writer,'Sheet1', index = False)
writer.save()